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Issue 26, 2017
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A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies

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Abstract

A new D3h-symmetry tris-N-heterocyclic carbene ligand has been prepared and coordinated to iridium and gold. The ligand contains an electron-poor hexaazatriphenylene core; thus, the resulting tris-NHC ligand is a poor electron donor. The tris–Au(I) complex was tested in the hydroamination of terminal alkynes and in the three-component Strecker reaction.

Graphical abstract: A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies

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Publication details

The article was received on 19 Jan 2017, accepted on 25 Feb 2017 and first published on 27 Feb 2017


Article type: Communication
DOI: 10.1039/C7CC00525C
Citation: Chem. Commun., 2017,53, 3733-3736
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    A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies

    S. Ibáñez, M. Poyatos and E. Peris, Chem. Commun., 2017, 53, 3733
    DOI: 10.1039/C7CC00525C

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