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Issue 27, 2017
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Dithiolato-bridged nickel–iron complexes as models for the active site of [NiFe]-hydrogenases

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Abstract

The structural and functional modeling of the active site of [NiFe]-hydrogenases has been proved to be challenging to a great extent. Herein, we report the synthesis, structures, and some properties of the NiFe-based dicarbonyl, terminal hydride, and μ-hydroxo models for the active site of [NiFe]-hydrogenases.

Graphical abstract: Dithiolato-bridged nickel–iron complexes as models for the active site of [NiFe]-hydrogenases

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Publication details

The article was received on 08 Jan 2017, accepted on 06 Mar 2017 and first published on 06 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC00149E
Citation: Chem. Commun., 2017,53, 3818-3821
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    Dithiolato-bridged nickel–iron complexes as models for the active site of [NiFe]-hydrogenases

    L. Song, X. Yang, M. Cao, X. Gao, B. Liu, L. Zhu and F. Jiang, Chem. Commun., 2017, 53, 3818
    DOI: 10.1039/C7CC00149E

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