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Issue 25, 2017
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Copper-catalyzed propargylation of diborylmethane

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Abstract

A Cu/PPh3-catalyzed propargylic substitution reaction of diborylmethane is reported. Different substituted propargyl electrophiles can be employed in this reaction, and various synthetic valuable functional groups can be tolerated. Di-deuterated diborylmethane can also be used under these conditions and generates α-deuterated alkylboronic esters in good yield.

Graphical abstract: Copper-catalyzed propargylation of diborylmethane

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Publication details

The article was received on 07 Jan 2017, accepted on 27 Feb 2017, published on 13 Mar 2017 and first published online on 13 Mar 2017


Article type: Communication
DOI: 10.1039/C7CC00129K
Citation: Chem. Commun., 2017,53, 3551-3554
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    Copper-catalyzed propargylation of diborylmethane

    F. Li, Z. Zhang, X. Lu, B. Xiao and Y. Fu, Chem. Commun., 2017, 53, 3551
    DOI: 10.1039/C7CC00129K

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