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Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines

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Abstract

A ligand controlled catalytic system for the aerobic oxidation of 1° amines to nitriles and imines has been developed where the varying π-acidic feature of BIAN versus phen in the frameworks of ruthenium catalysts facilitates switchable selectivity.

Graphical abstract: Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines

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Publication details

The article was received on 23 Dec 2016, accepted on 17 Mar 2017, published on 17 Mar 2017 and first published online on 17 Mar 2017


Article type: Communication
DOI: 10.1039/C6CC10200J
Citation: Chem. Commun., 2017, Advance Article
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    Ligand controlled switchable selectivity in ruthenium catalyzed aerobic oxidation of primary amines

    R. Ray, S. Chandra, V. Yadav, P. Mondal, D. Maiti and G. K. Lahiri, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C6CC10200J

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