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Issue 17, 2017
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Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks

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Abstract

Cu2O nanocubes were used for the synthesis of hollow and microporous Fe porphyrin networks (H–MFePN). In this synthesis, Cu2O nanocubes performed not only as networking catalysts but also as shape controlling templates. MFePN were formed on the surface of the Cu2O nanocubes through azide–alkyne cycloaddition of tetrakis(4-ethynylphenyl) Fe-porphyrin with 1,4-diazidobenzene. H–MFePN showed excellent catalytic activities in carbene insertion into N–H bonds, maintaining their activities during five recycle tests.

Graphical abstract: Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks

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Publication details

The article was received on 16 Dec 2016, accepted on 06 Feb 2017 and first published on 06 Feb 2017


Article type: Communication
DOI: 10.1039/C6CC10005H
Citation: Chem. Commun., 2017,53, 2598-2601
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    Dual role of Cu2O nanocubes as templates and networking catalysts for hollow and microporous Fe-porphyrin networks

    D. Kang, J. H. Ko, J. Choi, K. Cho, S. M. Lee, H. J. Kim, Y. Ko, K. H. Park and S. U. Son, Chem. Commun., 2017, 53, 2598
    DOI: 10.1039/C6CC10005H

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