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Issue 28, 2017
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1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration

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Abstract

A novel difunctionalization-type (hetero)arylation of unactivated alkenes has been developed via remote 1,4(5)-(hetero)aryl migration triggered by radical alkene azidation, trifluoromethylation, or phosphonylation. The overall process serves as an unusual and reliable approach for straightforward access to diversely substituted ketones with broad functional group compatibility from readily available substrates and reagents.

Graphical abstract: 1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration

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Publication details

The article was received on 18 Nov 2016, accepted on 13 Mar 2017 and first published on 15 Mar 2017


Article type: Communication
DOI: 10.1039/C6CC09215B
Citation: Chem. Commun., 2017,53, 4038-4041
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    1,2-Difunctionalization-type (hetero)arylation of unactivated alkenes triggered by radical addition/remote (hetero)aryl migration

    L. Li, Q. Gu, N. Wang, P. Song, Z. Li, X. Li, F. Wang and X. Liu, Chem. Commun., 2017, 53, 4038
    DOI: 10.1039/C6CC09215B

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