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Issue 12, 2017
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From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

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Abstract

Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation of the parent framework from a sodalite (SOD) network to a diamond (DIA) network.

Graphical abstract: From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

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Publication details

The article was received on 07 Nov 2016, accepted on 20 Jan 2017 and first published on 20 Jan 2017


Article type: Communication
DOI: 10.1039/C6CC08746A
Citation: Chem. Commun., 2017,53, 2028-2031
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    From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification

    M. Erkartal, U. Erkilic, B. Tam, H. Usta, O. Yazaydin, J. T. Hupp, O. K. Farha and U. Sen, Chem. Commun., 2017, 53, 2028
    DOI: 10.1039/C6CC08746A

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