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High molecular weight poly(N-methyl-B-vinylazaborine) – a semi-inorganic B–N polystyrene analogue

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Abstract

We present the synthesis of a B–N analogue of polystyrene, poly(N-methyl-B-vinylazaborine) in high molecular weight (MW = 24.9 kDa). Furthermore, it was possible to prepare a copolymer with the C–C analogue. A thorough comparison between the polymers by NMR spectroscopy, TGA, DSC and GPC showed significant differences between these polymers.

Graphical abstract: High molecular weight poly(N-methyl-B-vinylazaborine) – a semi-inorganic B–N polystyrene analogue

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Publication details

The article was received on 25 Oct 2016, accepted on 22 Dec 2016 and first published on 22 Dec 2016


Article type: Communication
DOI: 10.1039/C6CC08599G
Citation: Chem. Commun., 2017, Advance Article
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    High molecular weight poly(N-methyl-B-vinylazaborine) – a semi-inorganic B–N polystyrene analogue

    B. Thiedemann, P. J. Gliese, J. Hoffmann, P. G. Lawrence, F. D. Sönnichsen and A. Staubitz, Chem. Commun., 2017, Advance Article , DOI: 10.1039/C6CC08599G

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