Interaction of formaldehyde with a water-tolerant frustrated Lewis pair

Ghazi Ghattas; Claudia Bizzarri; Markus Hölscher; Jens Langanke; Christoph Gürtler; Walter Leitner; Muhammad Afzal Subhani

doi:10.1039/C6CC08044H

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Interaction of formaldehyde with a water-tolerant frustrated Lewis pair†

Ghazi Ghattas,^a Claudia Bizzarri,^a Markus Hölscher,^b Jens Langanke,^c Christoph Gürtler,^c Walter Leitner

^b and Muhammad Afzal Subhani

*^a

Author affiliations

* Corresponding authors

^a CAT Catalytic Center RWTH-Aachen University, Worringerweg 2, 52074 Aachen, Germany
E-mail: afzal.subhani@catalyticcenter.rwth-aachen.de

^b ITMC, RWTH Aachen University, Worringerweg 2, 52074 Aachen, Germany

^c COVESTRO Deutschland AG, Building B103, 51368 Leverkusen, Germany

Abstract

A facile complexation of formaldehyde with the water-tolerant frustrated Lewis pair (FLP) B(C₆F₅)₃/PtBu₃ and its Al-analog under ambient conditions is reported. Unprecedented formaldehyde adducts 1, 2 and 4 have been identified and crystallographically characterized.

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Article information

DOI: https://doi.org/10.1039/C6CC08044H
Article type: Communication
Submitted: 05 Oct 2016
Accepted: 10 Feb 2017
First published: 10 Feb 2017

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Chem. Commun., 2017,53, 3205-3208

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Interaction of formaldehyde with a water-tolerant frustrated Lewis pair

G. Ghattas, C. Bizzarri, M. Hölscher, J. Langanke, C. Gürtler, W. Leitner and M. A. Subhani, Chem. Commun., 2017, 53, 3205 DOI: 10.1039/C6CC08044H

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Chemical Communications

Interaction of formaldehyde with a water-tolerant frustrated Lewis pair†

Abstract

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Interaction of formaldehyde with a water-tolerant frustrated Lewis pair

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