Issue 2, 2017
From the journal:

Chemical Communications

Reduced thione ligation is preferred over neutral phosphine ligation in diiron biomimics regarding electronic functionality: a spectroscopic and computational investigation†

Tao-Hung Yen,abc   Zong-Cheng He,d   Gene-Hsiang Lee,e   Mei-Chun Tseng,a   Yu-Hsuan Shen,f   Tien-Wen Tseng,*d   Wen-Feng Liaw*c  and  Ming-Hsi Chiang*ab  

* Corresponding authors

a Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan
E-mail: mhchiang@chem.sinica.edu.tw

b Molecular Science Technology Program, TIGP, Institute of Chemistry, Academia Sinica, Nankang, Taipei 115, Taiwan

c Department of Chemistry, National Tsing Hua University, Hsinchu 300, Taiwan

d Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 106, Taiwan

e Instrumentation Center, National Taiwan University, Taipei 106, Taiwan

f Department of Chemistry, National Taiwan University, Taipei 106, Taiwan

Abstract

Sulfur containing ligands with a thiolate-thiyl radical character are much superior than phosphine ligands in the active site modeling of [FeFe]hydrogenase regarding electronic functionality on charge communication and modulation of the electronic structure of the catalytic metal center.

Graphical abstract: Reduced thione ligation is preferred over neutral phosphine ligation in diiron biomimics regarding electronic functionality: a spectroscopic and computational investigation

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Article information

DOI
https://doi.org/10.1039/C6CC08042A
Article type
Communication
Submitted
05 Oct 2016
Accepted
29 Nov 2016
First published
29 Nov 2016

Chem. Commun., 2017,53, 332-335

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Reduced thione ligation is preferred over neutral phosphine ligation in diiron biomimics regarding electronic functionality: a spectroscopic and computational investigation

T. Yen, Z. He, G. Lee, M. Tseng, Y. Shen, T. Tseng, W. Liaw and M. Chiang, Chem. Commun., 2017, 53, 332 DOI: 10.1039/C6CC08042A

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