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Novel method for standard addition signal analysis in voltammetry

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Abstract

A new procedure for standard addition analysis in voltammetry based on the slope of the peak at the inflection point (SSAA) is proposed. It is fully automated and does not require any subjective user decisions. It has been tested for both simulated and experimental data. Experimental data included DPASV measurements of Pb(II) and Cd(II) on RAgABE, and Tl(I) on BiABE as a working electrode. In each case the procedure offered good accuracy, precision and perfect reproducibility.

Graphical abstract: Novel method for standard addition signal analysis in voltammetry

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Publication details

The article was received on 01 Feb 2017, accepted on 22 Mar 2017 and first published on 22 Mar 2017


Article type: Paper
DOI: 10.1039/C7AN00185A
Citation: Analyst, 2017, Advance Article
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    Novel method for standard addition signal analysis in voltammetry

    F. Ciepiela and K. Węgiel, Analyst, 2017, Advance Article , DOI: 10.1039/C7AN00185A

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