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Issue 9, 2017
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Can all bulk-phase reactions be accelerated in microdroplets?

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Abstract

Recent studies have shown that microdroplet reactions are markedly accelerated compared to the corresponding bulk-phase reactions. This raises the question whether all reactions can be sped up by this means. We present a counter example, and we show that the reaction mechanism in microdroplets can differ sharply from that in bulk, especially because of the distinct microdroplet surface environment. This analysis helps to guide us how to choose and control reactions in microdroplets and provides a possible perspective on utilizing microdroplet chemistry to scale up synthesis.

Graphical abstract: Can all bulk-phase reactions be accelerated in microdroplets?

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Publication details

The article was received on 03 Oct 2016, accepted on 14 Mar 2017 and first published on 14 Mar 2017


Article type: Perspective
DOI: 10.1039/C6AN02225A
Citation: Analyst, 2017,142, 1399-1402
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    Can all bulk-phase reactions be accelerated in microdroplets?

    S. Banerjee, E. Gnanamani, X. Yan and R. N. Zare, Analyst, 2017, 142, 1399
    DOI: 10.1039/C6AN02225A

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