Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 42, 2016
Previous Article Next Article

Understanding the superior thermoelectric performance of Sb precipitated Ge17Sb2Te20

Author affiliations

Abstract

Composites were ruled out more than thirty years ago as a means of enhancing the figure-of-merit, and therefore conversion efficiency, of thermoelectric materials. However, recently it has been experimentally proven that the shortcomings of composite thermoelectric materials can be overcome using nanostructured secondary phases. Phase change materials, which have found applications in nonvolatile memory storage, have been identified as an alternative to Pb-based chalcogenide thermoelectric materials. Research has revealed that the thermoelectric figure-of-merit for these compounds can be increased using secondary phases in the absence of nanostructuring. The following work has studied the effects of secondary phases of Sb on the thermoelectric properties of Ge17Sb2Te20. This work has found that secondary phases of elemental Sb introduce additional charge carrier scattering that leads to increased power factor values and figure-of-merit values in excess of a factor of 2, further emphasizing the importance of revisiting composites for enhancing the performance of thermoelectric materials.

Graphical abstract: Understanding the superior thermoelectric performance of Sb precipitated Ge17Sb2Te20

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 01 Sep 2016, accepted on 06 Oct 2016 and first published on 12 Oct 2016


Article type: Paper
DOI: 10.1039/C6TC03789E
Citation: J. Mater. Chem. C, 2016,4, 10011-10017
  •   Request permissions

    Understanding the superior thermoelectric performance of Sb precipitated Ge17Sb2Te20

    J. B. Williams and D. T. Morelli, J. Mater. Chem. C, 2016, 4, 10011
    DOI: 10.1039/C6TC03789E

Search articles by author