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Issue 32, 2016
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Insights into the correlation between the molecular conformational change and AIE activity of 2,5-bis(dimesitylboryl)-3,4-diphenylsiloles

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Abstract

Three novel AIEgens with low-lying LUMO energy levels are developed from p-π conjugated 2,5-bis(dimesitylboryl)-3,4-diphenylsiloles. It is found that intramolecular interactions lower the molecular conformational changes, giving rise to broad 1H NMR peaks and decreased AIE activity.

Graphical abstract: Insights into the correlation between the molecular conformational change and AIE activity of 2,5-bis(dimesitylboryl)-3,4-diphenylsiloles

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Publication details

The article was received on 01 Jul 2016, accepted on 24 Jul 2016 and first published on 25 Jul 2016


Article type: Communication
DOI: 10.1039/C6TC02738E
Citation: J. Mater. Chem. C, 2016,4, 7541-7545
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    Insights into the correlation between the molecular conformational change and AIE activity of 2,5-bis(dimesitylboryl)-3,4-diphenylsiloles

    B. Chen, H. Nie, R. Hu, A. Qin, Z. Zhao and B. Z. Tang, J. Mater. Chem. C, 2016, 4, 7541
    DOI: 10.1039/C6TC02738E

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