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Issue 5, 2017
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Carambola-shaped VO2 nanostructures: a binder-free air electrode for an aqueous Na–air battery

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Abstract

Binder-free and bifunctional electrocatalysts have vital roles in the development of high-performance metal–air batteries. Herein, we synthesized a vanadium oxide (VO2) nanostructure as a novel binder-free and bifunctional electrocatalyst for a rechargeable aqueous sodium–air (Na–air) battery. VO2 nanostructures were grown on reduced graphene oxide coated on carbon paper, which had a carambola morphology. We confirmed the bifunctional nature of VO2 nanostructures by analyzing their electrocatalytic activity associated with the oxygen reduction reaction and oxygen evolution reaction. The reaction pathway associated with electrocatalytic activity was also affirmed by computational modeling and simulation studies. Thereafter, an aqueous Na–air cell was built using novel binder-free VO2 nanostructures as the air electrode. The fabricated cell displayed a 0.64 V overpotential gap, 104 mW g−1 power density at 80 mA g−1 current density, 81% round trip efficiency and good cyclic stability up to 50 cycles.

Graphical abstract: Carambola-shaped VO2 nanostructures: a binder-free air electrode for an aqueous Na–air battery

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Publication details

The article was received on 29 Oct 2016, accepted on 18 Dec 2016 and first published on 19 Dec 2016


Article type: Paper
DOI: 10.1039/C6TA09375B
Citation: J. Mater. Chem. A, 2017,5, 2037-2044
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    Carambola-shaped VO2 nanostructures: a binder-free air electrode for an aqueous Na–air battery

    Z. Khan, B. Senthilkumar, S. O. Park, S. Park, J. Yang, J. H. Lee, H. Song, Y. Kim, S. K. Kwak and H. Ko, J. Mater. Chem. A, 2017, 5, 2037
    DOI: 10.1039/C6TA09375B

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