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Issue 28, 2016
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Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties

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Abstract

The first example of a spiropyran-incorporated metal–organic framework was synthesised via a two-step post-synthesis modification of the Zr-oxo nodes in MOF-808. The incorporated spiropyran could not otherwise be obtained via the analogous one-step de novo synthesis. The resulting MOF-808-SP showed a photoresponsive surface area, pore volume and CO2 uptake, relevant for light-dependent gas separations processes.

Graphical abstract: Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties

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Publication details

The article was received on 19 May 2016, accepted on 22 Jun 2016 and first published on 04 Jul 2016


Article type: Communication
DOI: 10.1039/C6TA04160D
Author version available: Download Author version (PDF)
Citation: J. Mater. Chem. A, 2016,4, 10816-10819
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    Photoresponsive spiropyran-functionalised MOF-808: postsynthetic incorporation and light dependent gas adsorption properties

    K. Healey, W. Liang, P. D. Southon, T. L. Church and D. M. D'Alessandro, J. Mater. Chem. A, 2016, 4, 10816
    DOI: 10.1039/C6TA04160D

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