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Issue 26, 2016
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Inexpensive polyphenylene network polymers with enhanced microporosity

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Abstract

Greatly enhanced microporosity is obtained for the amorphous porous polymers produced from the AlCl3-mediated coupling of aromatic hydrocarbons by using dichloromethane as the reaction solvent. A polymer of average BET surface area = 2435 m2 g−1 was obtained reproducibly from 1,3,5-triphenylbenzene with the additional porosity being provided as ultramicroporosity as demonstrated by very high CO2 adsorption at 273 K/1 bar.

Graphical abstract: Inexpensive polyphenylene network polymers with enhanced microporosity

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Publication details

The article was received on 19 Apr 2016, accepted on 13 Jun 2016 and first published on 17 Jun 2016


Article type: Communication
DOI: 10.1039/C6TA03257E
Citation: J. Mater. Chem. A, 2016,4, 10110-10113
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    Inexpensive polyphenylene network polymers with enhanced microporosity

    K. J. Msayib and N. B. McKeown, J. Mater. Chem. A, 2016, 4, 10110
    DOI: 10.1039/C6TA03257E

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