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Issue 17, 2016
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Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption

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Abstract

Two microporous covalent triazine-based frameworks (CTFs) with triptycene (TPC) and fluorene (FL) backbones have been synthesized through a mild AlCl3-catalyzed Friedel–Crafts reaction, with the highest surface area of up to 1668 m2 g−1 for non-ionothermal CTFs. CTF-TPC and CTF-FL show an excellent carbon dioxide uptake capacity of up to 4.24 mmol g−1 at 273 K and 1 bar.

Graphical abstract: Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption

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Publication details

The article was received on 22 Jan 2016, accepted on 30 Mar 2016 and first published on 31 Mar 2016


Article type: Communication
DOI: 10.1039/C6TA00638H
Citation: J. Mater. Chem. A, 2016,4, 6259-6263
  • Open access: Creative Commons BY-NC license
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    Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption

    S. Dey, A. Bhunia, D. Esquivel and C. Janiak, J. Mater. Chem. A, 2016, 4, 6259
    DOI: 10.1039/C6TA00638H

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