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Issue 42, 2016
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Determination of physical emulsion stabilization mechanisms of wood hemicelluloses via rheological and interfacial characterization

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Abstract

Materials manufacturing industries seek efficient, economic, and sustainable compounds for stabilizing dispersed systems such as emulsions. In this study, novel, abundant biobased hydrocolloids spruce galactoglucomannans (GGM) and birch glucuronoxylans (GX) were obtained from a forestry biorefining process and characterized as versatile stabilizers of rapeseed oil-in-water emulsions. For the first time, GGM and GX isolated by pressurized hot water extraction (PHWE) of spruce and birch saw meal, respectively, were studied in emulsions. The PHWE wood hemicelluloses—polysaccharides with relatively low molar mass—facilitated the formation of emulsions with small average droplet size and efficiently prevented droplet coalescence. GGM and GX lowered the surface tension of emulsions' oil–water interface and increased the viscosity of the continuous phase. However, viscosity of the wood hemicellulose-based systems was low compared to that of commercial polymeric stabilizers. GGM-stabilized emulsions with varying oil volume fractions were characterized in terms of their rheological properties, including large amplitude oscillation shear (LAOS) measurements, and compared to emulsions prepared with a classical small-molecular surfactant, Tween20. The physical emulsion stabilization mechanisms of GGM and GX are suggested as steric repulsion assisted by Pickering-type stabilization. Wood hemicelluloses have potential as highly promising future bioproducts for versatile industrial applications involving colloidal systems and soft materials.

Graphical abstract: Determination of physical emulsion stabilization mechanisms of wood hemicelluloses via rheological and interfacial characterization

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Publication details

The article was received on 07 Jul 2016, accepted on 19 Sep 2016, published on 20 Sep 2016 and first published online on 20 Sep 2016


Article type: Paper
DOI: 10.1039/C6SM01557C
Citation: Soft Matter, 2016,12, 8690-8700
  • Open access: Creative Commons BY license
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    Determination of physical emulsion stabilization mechanisms of wood hemicelluloses via rheological and interfacial characterization

    K. S. Mikkonen, D. Merger, P. Kilpeläinen, L. Murtomäki, U. S. Schmidt and M. Wilhelm, Soft Matter, 2016, 12, 8690
    DOI: 10.1039/C6SM01557C

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