Jump to main content
Jump to site search

Issue 1, 2017
Previous Article Next Article

Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

Author affiliations

Abstract

The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single diastereoisomer.

Graphical abstract: Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 15 Jun 2016, accepted on 04 Aug 2016 and first published on 30 Aug 2016


Article type: Edge Article
DOI: 10.1039/C6SC02617F
Citation: Chem. Sci., 2017,8, 334-339
  • Open access: Creative Commons BY license
  •   Request permissions

    Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

    S. R. Roy, H. Eijsberg, J. Bruffaerts and I. Marek, Chem. Sci., 2017, 8, 334
    DOI: 10.1039/C6SC02617F

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author