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Issue 106, 2016, Issue in Progress
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Structure-induced catalysis enhancement of Cu-amino catalysts for rapidly selective oxidation of sulfides in the presence of H2O2

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Abstract

With benzyl phenyl sulfide as a model substrate and H2O2 as an oxidant, high selectivity toward the desired sulfoxide is obtained when using two CuII-amino acid complexes as catalysts, while strong stereospecific obstruction in a 1D helical array of complex 2 enables speedy sulfoxidation with excellent conversion.

Graphical abstract: Structure-induced catalysis enhancement of Cu-amino catalysts for rapidly selective oxidation of sulfides in the presence of H2O2

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The article was received on 07 Sep 2016, accepted on 17 Oct 2016 and first published on 18 Oct 2016


Article type: Communication
DOI: 10.1039/C6RA22393A
Citation: RSC Adv., 2016,6, 104036-104040
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    Structure-induced catalysis enhancement of Cu-amino catalysts for rapidly selective oxidation of sulfides in the presence of H2O2

    Z. Zhang, X. Yang, Q. Zhang, L. Wang, M. He, Q. Chen and X. Huang, RSC Adv., 2016, 6, 104036
    DOI: 10.1039/C6RA22393A

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