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Issue 102, 2016, Issue in Progress
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Synthesis and characterization of two novel second-order nonlinear optical chromophores based on julolidine donors with excellent electro-optic activity

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Abstract

Julolidine and its derivatives are excellent electron-rich structures thus two novel second order nonlinear optical (NLO) chromophores based on julolidine donors and tricyanofuran (TCF) acceptors linked via isophorone bridge (zh-1) and modified isophorone bridge (zh-2) have been synthesized. Density functional theory (DFT) was used to optimize the geometrical structures, calculate the HOMO–LUMO energy gaps and first-order hyperpolarizability (β) of these chromophores. Besides, to determine the redox properties of these chromophores, cyclic voltammetry (CV) experiments were performed. The optimized structures suggest that chromophore zh-1 possesses better planarity which increases the ability of electron delocalization. These chromophores showed good thermal stability with their decomposition temperatures all above 210 °C. The electro-optic coefficients (r33) of poled films containing 25 wt% of these chromophores doped in amorphous polycarbonate (APC) afforded values of 170 and 101 pm V−1 at 1310 nm for chromophores zh-1 and zh-2, respectively. These properties show the potential use of the new chromophores as advanced material devices.

Graphical abstract: Synthesis and characterization of two novel second-order nonlinear optical chromophores based on julolidine donors with excellent electro-optic activity

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Publication details

The article was received on 31 Aug 2016, accepted on 10 Oct 2016 and first published on 10 Oct 2016


Article type: Paper
DOI: 10.1039/C6RA21814H
Citation: RSC Adv., 2016,6, 99743-99751
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    Synthesis and characterization of two novel second-order nonlinear optical chromophores based on julolidine donors with excellent electro-optic activity

    H. Zhang, F. Huo, F. Liu, Z. Chen, J. Liu, S. Bo, Z. Zhen and L. Qiu, RSC Adv., 2016, 6, 99743
    DOI: 10.1039/C6RA21814H

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