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Issue 105, 2016, Issue in Progress
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3-D structured SnO2–polypyrrole nanotubes applied in Na-ion batteries

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Abstract

SnO2-coated polypyrrole (PPy) with a three-dimensional (3-D) structured nanotube network has been prepared via a facile hydrothermal method and tested as an anode material for Na-ion batteries. The crystalline SnO2 nanoparticles (less than 25 nm in size) are distributed uniformly on the surfaces of the PPy tubes. When it is used as an anode material for sodium-ion batteries (SIBs), the composite electrode can deliver a good reversible capacity of nearly 288 mA h g−1 when discharging at 100 mA g−1, with more than 69.1% capacity retention and stable coulombic efficiency of 99.6% after 150 cycles. The good electrochemical performance compared to the 151 mA h g−1 achieved by bare SnO2, which was fabricated by the same method in the absence of PPy, could be mainly attributed to the good dispersion of SnO2 on the 3-D matrix of PPy tubes, which facilitates the diffusion of Na+ ions and buffers the large volumetric changes during charge/discharge. Our results suggest that such SnO2/carbonaceous composites would be good anode candidates for SIBs.

Graphical abstract: 3-D structured SnO2–polypyrrole nanotubes applied in Na-ion batteries

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Publication details

The article was received on 23 Aug 2016, accepted on 17 Oct 2016 and first published on 18 Oct 2016


Article type: Paper
DOI: 10.1039/C6RA21139A
Citation: RSC Adv., 2016,6, 103124-103131
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    3-D structured SnO2–polypyrrole nanotubes applied in Na-ion batteries

    B. Ruan, H. Guo, Q. Liu, D. Shi, S. Chou, H. Liu, G. Chen and J. Wang, RSC Adv., 2016, 6, 103124
    DOI: 10.1039/C6RA21139A

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