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Issue 104, 2016, Issue in Progress
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An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition

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Abstract

A novel protocol to synthesize tert-butyl esters from benzyl cyanides and tert-butyl hydroperoxide has been successfully achieved. In the presence of tert-butyl hydroperoxide, Csp3–H bond oxidation, C–CN bond cleavage and C–O bond formation proceeded smoothly in one pot under the metal-free condition.

Graphical abstract: An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition

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Publication details

The article was received on 20 Aug 2016, accepted on 26 Sep 2016 and first published on 10 Oct 2016


Article type: Communication
DOI: 10.1039/C6RA20966A
Citation: RSC Adv., 2016,6, 102023-102027
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    An efficient method for the preparation of tert-butyl esters from benzyl cyanide and tert-butyl hydroperoxide under the metal free condition

    X. Chen, Y. Li, M. Wu, H. Guo, L. Jiang, J. Wang and S. Sun, RSC Adv., 2016, 6, 102023
    DOI: 10.1039/C6RA20966A

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