The Cu-catalyzed hydroboration of alkynes in operationally simple and environmentally friendly conditions is reported. The reactions are performed in water, at room temperature, under micellar catalysis. Conditions to form the α or β borylated products selectively have been found and as an application a protocol for the tandem hydroboration/Suzuki coupling in water was developed.
J. S. da Costa, R. K. Braun, P. A. Horn, D. S. Lüdtke and A. V. Moro, RSC Adv., 2016, 6, 59935 DOI: 10.1039/C6RA14465A
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