Issue 59, 2016, Issue in Progress
From the journal:

RSC Advances

Ru-Catalyzed highly site-selective C–H bond arylation of 9-(pyrimidin-2-yl)-9H-carbazole†

K. Harsha Vardhan Reddy,*a   R. Uday Kumar,a   V. Prakash Reddy,a   G. Satish,a   Jagadeesh Babu Nanubolub  and  Y. V. D. Nageswar*a  

* Corresponding authors

a MCP Division, Indian Institute of Chemical Technology, Hyderabad 500607, India
E-mail: drharshaindia@gmail.com, dryvdnageswar@gmail.com
Fax: +91-40-27160512

b X-ray Crystallography, Indian Institute of Chemical Technology, Hyderabad 500007, India

Abstract

We describe here an efficient ruthenium-catalyzed C–H bond ortho-arylation of 9-(pyrimidin-2-yl)-9H-carbazole by using boronic acids. This methodology exhibits excellent and high site-selectivity, functional group tolerance and was found to give the desired product in moderate to good yields.

Graphical abstract: Ru-Catalyzed highly site-selective C–H bond arylation of 9-(pyrimidin-2-yl)-9H-carbazole

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Article information

DOI
https://doi.org/10.1039/C6RA09825H
Article type
Paper
Submitted
15 Apr 2016
Accepted
18 May 2016
First published
19 May 2016

RSC Adv., 2016,6, 54431-54434

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Ru-Catalyzed highly site-selective C–H bond arylation of 9-(pyrimidin-2-yl)-9H-carbazole

K. Harsha Vardhan Reddy, R. U. Kumar, V. P. Reddy, G. Satish, J. B. Nanubolu and Y. V. D. Nageswar, RSC Adv., 2016, 6, 54431 DOI: 10.1039/C6RA09825H

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