H2 activation using the first 1 : 1 : 1 hetero-tri(aryl)borane

Robin J. Blagg; Gregory G. Wildgoose

doi:10.1039/C6RA07007H

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H₂ activation using the first 1 : 1 : 1 hetero-tri(aryl)borane†

Robin J. Blagg

*^a and Gregory G. Wildgoose*^a

Author affiliations

* Corresponding authors

^a School of Chemistry, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK
E-mail: r.blagg@uea.ac.uk, g.wildgoose@uea.ac.uk

Abstract

The novel 1 : 1 : 1 hetero-tri(aryl)borane (pentafluorophenyl){3,5-bis(trifluoromethyl)phenyl}(pentachlorophenyl)borane has been synthesised and structurally characterised. This has been show to act as the Lewis acidic component in FLPs for the heterolytic cleavage of H₂ with three Lewis bases.

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Article information

DOI: https://doi.org/10.1039/C6RA07007H
Article type: Paper
Submitted: 16 Mar 2016
Accepted: 20 Apr 2016
First published: 28 Apr 2016
This article is Open Access

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RSC Adv., 2016,6, 42421-42427

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H₂ activation using the first 1 : 1 : 1 hetero-tri(aryl)borane

R. J. Blagg and G. G. Wildgoose, RSC Adv., 2016, 6, 42421 DOI: 10.1039/C6RA07007H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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