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Issue 11, 2016
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A highly efficient one-pot trifluoromethylation/cyclization reaction of electron-deficient 1,3-conjugated enynes: modular access to trifluoromethylated furans and 2,3-dihydrofurans

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Abstract

A highly efficient one-pot trifluoromethylation/cyclization reaction of conjugated enyne aldehydes and ketones was developed, which provides modular access to highly substituted trifluoromethylated furans and 2,3-dihydrofurans. This method has the advantages of mild reaction conditions, wide functional group tolerance, high yields and being transition metal free.

Graphical abstract: A highly efficient one-pot trifluoromethylation/cyclization reaction of electron-deficient 1,3-conjugated enynes: modular access to trifluoromethylated furans and 2,3-dihydrofurans

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Publication details

The article was received on 22 Jul 2016, accepted on 22 Aug 2016 and first published on 23 Aug 2016


Article type: Research Article
DOI: 10.1039/C6QO00385K
Citation: Org. Chem. Front., 2016,3, 1416-1419
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    A highly efficient one-pot trifluoromethylation/cyclization reaction of electron-deficient 1,3-conjugated enynes: modular access to trifluoromethylated furans and 2,3-dihydrofurans

    W. Zhou, Z. Yue and J. Zhang, Org. Chem. Front., 2016, 3, 1416
    DOI: 10.1039/C6QO00385K

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