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Issue 11, 2016
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A copper(II)-catalyzed three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes

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Abstract

A three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes catalyzed by copper(II) bromide is developed, which provides an efficient route to (E)-alkenyl sulfones or allylic sulfones via the insertion of sulfur dioxide. A radical process is believed to be involved in the reaction.

Graphical abstract: A copper(ii)-catalyzed three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes

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Publication details

The article was received on 12 Jul 2016, accepted on 06 Sep 2016 and first published on 07 Sep 2016


Article type: Research Article
DOI: 10.1039/C6QO00350H
Citation: Org. Chem. Front., 2016,3, 1498-1502
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    A copper(II)-catalyzed three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes

    R. Mao, Z. Yuan, R. Zhang, Y. Ding, X. Fan and J. Wu, Org. Chem. Front., 2016, 3, 1498
    DOI: 10.1039/C6QO00350H

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