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Issue 11, 2016
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Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions

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Abstract

A highly efficient manganese-catalysed hydroperoxidation of carbon–carbon double bonds of enynes as well as styrene derivatives using N-hydroxyphthalimide, N-hydroxybenzotriazole or N-hydroxysuccinimide was developed. This reaction proceeded at room temperature through the direct incorporation of molecular oxygen present in air. The required catalytic loading of manganese(III) acetylacetonate is extremely low (generally 0.02–0.5 mol%, and a minimum of 0.001 mol%).

Graphical abstract: Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions

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Publication details

The article was received on 30 Jun 2016, accepted on 22 Aug 2016 and first published on 23 Aug 2016


Article type: Research Article
DOI: 10.1039/C6QO00318D
Citation: Org. Chem. Front., 2016,3, 1420-1424
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    Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions

    D. Yamamoto, M. Soga, H. Ansai and K. Makino, Org. Chem. Front., 2016, 3, 1420
    DOI: 10.1039/C6QO00318D

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