Jump to main content
Jump to site search

Issue 11, 2016
Previous Article Next Article

Mesoporous SiO2/carbon hollow spheres applied towards a high rate-performance Li-battery anode

Author affiliations

Abstract

Mesoporous SiO2/C hollow spheres have been successfully synthesized via a one-step template process and carbonization of a mesoporous SiO2/poly(ethylene oxide)/phenolic formaldehyde resin hollow nanocomposite, and then evaluated as anode materials for lithium-ion batteries. The continuous carbon framework significantly led the SiO2/C hollow spheres to reach a high conductivity (3.9 × 10−4 S cm−1) compared with the SiO2 hollow spheres (<10−9 S cm−1), furthermore, the unique hollow nanostructure with a large volume interior and numerous mesopores plugged with carbon in the silica shell, could accommodate the volume variation and improve the structural strain for Li ion conduction, as well as allow rapid access of Li ions during charge–discharge cycling. For battery applications, at 100 mA g−1 charge/discharge rates, the reversible capacity of this mesoporous SiO2/C anode (624 mA h g−1) is over ten times higher than that of the SiO2 anode (61 mA h g−1). More specifically, even under the high discharge rate of 3000 mA g−1, this SiO2/C hollow nanostructure exhibits a specific capacity of 582 mA h g−1, featuring a high retention of more than 90% of its low discharge rate of 100 mA g−1. This demonstrates that the effective conduction of electrons through the continuous carbon network and the fast transport of Li ions through the nanoscale SiO2 shell significantly contribute to the high-rate performance.

Graphical abstract: Mesoporous SiO2/carbon hollow spheres applied towards a high rate-performance Li-battery anode

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 11 May 2016, accepted on 04 Sep 2016, published on 21 Sep 2016 and first published online on 21 Sep 2016


Article type: Research Article
DOI: 10.1039/C6QI00125D
Citation: Inorg. Chem. Front., 2016,3, 1398-1405
  •   Request permissions

    Mesoporous SiO2/carbon hollow spheres applied towards a high rate-performance Li-battery anode

    C. Wang, K. Liu, W. Chen, J. Zhou, H. Lin, C. Hsu and P. Kuo, Inorg. Chem. Front., 2016, 3, 1398
    DOI: 10.1039/C6QI00125D

Search articles by author