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Issue 6, 2016
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Isostructural compartmentalized spin-crossover coordination polymers for gas confinement

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Abstract

Here we present two FeII coordination polymers that possess discrete compartments suitable for CO2 physisorption despite the lack of permanent channels. The two crystalline materials, of general formula [Fe(btzbp)3](X)2 (X = ClO4 or BF4), present voids of ca. 250 Å3, which each can accommodate up to two CO2 molecules. The abrupt spin transition can be modified upon CO2 sorption, and different magnetic behaviour is observed depending on the number of molecules sorbed.

Graphical abstract: Isostructural compartmentalized spin-crossover coordination polymers for gas confinement

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The article was received on 04 Dec 2015, accepted on 22 Feb 2016 and first published on 14 Mar 2016


Article type: Research Article
DOI: 10.1039/C5QI00277J
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Citation: Inorg. Chem. Front., 2016,3, 808-813
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    Isostructural compartmentalized spin-crossover coordination polymers for gas confinement

    N. Calvo Galve, M. Giménez-Marqués, M. Palomino, S. Valencia, F. Rey, G. Mínguez Espallargas and E. Coronado, Inorg. Chem. Front., 2016, 3, 808
    DOI: 10.1039/C5QI00277J

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