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Issue 1, 2016
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Magnetization dynamics of a heterometallic Dy-isocarbonyl complex

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Abstract

The reaction of Dy(N(Si(CH3)3)2)3 with three equivalents of HW(CO)3Cp (Cp = cyclopentadienyl) furnished the first structurally characterized isocarbonyl complex of Dy3+, [{CpW(CO)2(μ-CO)}3Dy(thf)5] (1). Solid dilution via cocrystallization with the isostrucutral Y3+ analogue of 1 allowed for the observation of temperature dependent signals in the out-of-phase component of the ac magnetic susceptibility in the presence of an applied dc field. An effective barrier to magnetization reversal of 12.6 cm−1 could be extracted for compound 1 under these conditions.

Graphical abstract: Magnetization dynamics of a heterometallic Dy-isocarbonyl complex

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Publication details

The article was received on 29 Oct 2015, accepted on 03 Dec 2015 and first published on 07 Dec 2015


Article type: Research Article
DOI: 10.1039/C5QI00224A
Author version available: Download Author version (PDF)
Citation: Inorg. Chem. Front., 2016,3, 97-103
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    Magnetization dynamics of a heterometallic Dy-isocarbonyl complex

    C. M. Dickie and M. Nippe, Inorg. Chem. Front., 2016, 3, 97
    DOI: 10.1039/C5QI00224A

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