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Issue 48, 2016
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Cu(I)-Catalyzed amino-yne click polymerization

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Abstract

The hydroamination reaction of alkynes has been widely studied, but has not been developed as a powerful tool for polymer synthesis. Herein, a novel Cu(I)-catalyzed polyhydroamination has been developed for the facile preparation of nitrogen-containing polymers. This polymerization proceeded smoothly in bulk with 100% atom utilization in a regio-specific and stereo-selective fashion, producing polyenamines with well-defined structures and high molecular weights (up to 13 470) in high yields (up to 97%). Thus, this polymerization is a kind of amino-yne click polymerization. The resulting polymers possess excellent solubility, high thermal stability, strong UV-light shielding efficiency, and good visible light transparency. Considering the high efficiency, ready monomer availability and excellent performance of the products, this Cu(I)-catalyzed amino-yne click polymerization opens up enormous opportunities for preparing functional polymers.

Graphical abstract: Cu(i)-Catalyzed amino-yne click polymerization

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Publication details

The article was received on 27 Aug 2016, accepted on 13 Sep 2016 and first published on 14 Sep 2016


Article type: Paper
DOI: 10.1039/C6PY01501H
Citation: Polym. Chem., 2016,7, 7375-7382
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    Cu(I)-Catalyzed amino-yne click polymerization

    B. He, S. Zhen, Y. Wu, R. Hu, Z. Zhao, A. Qin and B. Z. Tang, Polym. Chem., 2016, 7, 7375
    DOI: 10.1039/C6PY01501H

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