Issue 45, 2016
From the journal:

Organic & Biomolecular Chemistry

Palladium-catalyzed decarboxylative ortho-arylation of 2-pyridyl sulfoxides with benzoyl peroxides†

Meng Sun,*a   Zhe Wang,a   Jiaxin Wang,a   Peiyu Guo,a   Xiangxiang Chena  and  Ya-Min Lib  

* Corresponding authors

a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Department of Chemistry & Materials Science, Northwest University, Xi'an 710127, P. R. China
E-mail: sunmeng@nwu.edu.cn

b Faculty of Life Science and Technology, Kunming University of Science and Technology, 727 Jingming Nanlu, Kunming 650500, P. R. China

Abstract

A palladium catalyzed efficient strategy for regio-selective ortho-arylation of sulfoxides with benzoyl peroxides via decarboxylation has been developed. This reaction proceeds smoothly, tolerates a variety of functional groups, and provides easy access to the synthesis of different biaryl compounds.

Graphical abstract: Palladium-catalyzed decarboxylative ortho-arylation of 2-pyridyl sulfoxides with benzoyl peroxides

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Article information

DOI
https://doi.org/10.1039/C6OB02040B
Article type
Communication
Submitted
18 Sep 2016
Accepted
26 Oct 2016
First published
26 Oct 2016

Org. Biomol. Chem., 2016,14, 10585-10588

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Palladium-catalyzed decarboxylative ortho-arylation of 2-pyridyl sulfoxides with benzoyl peroxides

M. Sun, Z. Wang, J. Wang, P. Guo, X. Chen and Y. Li, Org. Biomol. Chem., 2016, 14, 10585 DOI: 10.1039/C6OB02040B

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