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Issue 42, 2016
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Novel and efficient transformation of enamides into α-acyloxy ketones via an acyl intramolecular migration process

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Abstract

Hydrogen peroxide and anhydride mediated transformation of enamides to afford substituted α-acyloxy ketones is described. This transition-metal-free cascade reaction has a broad substrate scope and high efficiency. The acyl intramolecular migration procedure successfully achieved this acyloxylation process under mild conditions and increased the atom efficiency.

Graphical abstract: Novel and efficient transformation of enamides into α-acyloxy ketones via an acyl intramolecular migration process

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Publication details

The article was received on 12 Sep 2016, accepted on 30 Sep 2016 and first published on 30 Sep 2016


Article type: Paper
DOI: 10.1039/C6OB02002J
Citation: Org. Biomol. Chem., 2016,14, 10070-10073
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    Novel and efficient transformation of enamides into α-acyloxy ketones via an acyl intramolecular migration process

    X. Zhou, H. Ma, J. Cao, X. Liu and G. Huang, Org. Biomol. Chem., 2016, 14, 10070
    DOI: 10.1039/C6OB02002J

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