Issue 40, 2016
From the journal:

Organic & Biomolecular Chemistry

Rhodium(iii)-catalyzed ortho-alkenylation using a cyclic N-phosphoryl ketimine as the directing group†

Yu-Qin Zhu,‡a   Liu Qin,‡a   Qiang Song,a   Fu Su,a   Yan-Jun Xu*b  and  Lin Dong*a  

* Corresponding authors

a Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry, West China School of Pharmacy, Sichuan University, Chengdu 610041, China
E-mail: dongl@scu.edu.cn

b Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Urumqi, China

Abstract

A novel cyclic N-phosphoryl ketimine structure can efficiently react with olefins as useful directing groups to construct a myriad of phosphate scaffolds via rhodium(III)-catalyzed ortho-alkenylation. This method provides a probability that the coupling products could be used as a building block to access more complex organic phosphorus compounds.

Graphical abstract: Rhodium(iii)-catalyzed ortho-alkenylation using a cyclic N-phosphoryl ketimine as the directing group

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Article information

DOI
https://doi.org/10.1039/C6OB01899H
Article type
Communication
Submitted
29 Aug 2016
Accepted
20 Sep 2016
First published
20 Sep 2016

Org. Biomol. Chem., 2016,14, 9472-9475

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Rhodium(III)-catalyzed ortho-alkenylation using a cyclic N-phosphoryl ketimine as the directing group

Y. Zhu, L. Qin, Q. Song, F. Su, Y. Xu and L. Dong, Org. Biomol. Chem., 2016, 14, 9472 DOI: 10.1039/C6OB01899H

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