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Issue 42, 2016
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A red fluorophore comprising a borinate-containing xanthene analogue as a polyol sensor

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Abstract

A xanthene derivative containing a borinate moiety emitted red fluorescence with a high quantum yield. The interaction between the borinate and a sugar molecule induced a fluorescence change based on the change in the HOMO–LUMO gap. The response was pH-resistant in a wide range. In addition, catechol quenched through photoinduced electron transfer. The red fluorescence and polyol binding ability of dyes will pave the way for new biological applications of chemical sensors.

Graphical abstract: A red fluorophore comprising a borinate-containing xanthene analogue as a polyol sensor

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Publication details

The article was received on 06 Aug 2016, accepted on 27 Sep 2016 and first published on 27 Sep 2016


Article type: Paper
DOI: 10.1039/C6OB01695B
Citation: Org. Biomol. Chem., 2016,14, 10031-10036
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    A red fluorophore comprising a borinate-containing xanthene analogue as a polyol sensor

    N. Shimomura, Y. Egawa, R. Miki, T. Fujihara, Y. Ishimaru and T. Seki, Org. Biomol. Chem., 2016, 14, 10031
    DOI: 10.1039/C6OB01695B

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