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Issue 24, 2016
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anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(III) reagents

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Abstract

anti-Selective aminofluorination of alkenes with amidines was enabled by hypervalent iodine(III) reagents, affording 4-fluoroalkyl-2-imidazolines. Further reductive ring-opening of the 2-imidazoline moiety could deliver highly functionalized 3-fluoropropane-1,2-diamine derivatives.

Graphical abstract: anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(iii) reagents

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Publication details

The article was received on 05 Sep 2015, accepted on 24 Sep 2015 and first published on 24 Sep 2015


Article type: Communication
DOI: 10.1039/C5OB01854D
Author version available: Download Author version (PDF)
Citation: Org. Biomol. Chem., 2016,14, 5481-5485
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    anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine(III) reagents

    H. Chen, A. Kaga and S. Chiba, Org. Biomol. Chem., 2016, 14, 5481
    DOI: 10.1039/C5OB01854D

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