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Issue 44, 2016
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Selective hydrogenation of the C[double bond, length as m-dash]C bond in α,β-unsaturated aldehydes and ketones over ultra-small Pd–Au clusters

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Abstract

Pd–Au clusters of 1.8 nm preferentially catalyzed the hydrogenation of the C[double bond, length as m-dash]C bond in α,β-unsaturated aldehydes and ketones with a selectivity of ∼99%, primarily because of the unique electronic properties and isolated Pd ensembles on the ultra-small alloyed particles.

Graphical abstract: Selective hydrogenation of the C [[double bond, length as m-dash]] C bond in α,β-unsaturated aldehydes and ketones over ultra-small Pd–Au clusters

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Publication details

The article was received on 05 Sep 2016, accepted on 14 Oct 2016 and first published on 18 Oct 2016


Article type: Communication
DOI: 10.1039/C6NR07013B
Citation: Nanoscale, 2016,8, 18626-18629
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    Selective hydrogenation of the C[double bond, length as m-dash]C bond in α,β-unsaturated aldehydes and ketones over ultra-small Pd–Au clusters

    Y. Zhang, X. Yang, Y. Zhou, G. Li, Z. Li, C. Liu, M. Bao and W. Shen, Nanoscale, 2016, 8, 18626
    DOI: 10.1039/C6NR07013B

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