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Issue 12, 2016
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BMIm HCO3: an ionic liquid with carboxylating properties. Synthesis of carbamate esters from amines

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Abstract

1-Butyl-3-methylimidazolium hydrogen carbonate (BMIm HCO3) was used as an ionic liquid with carboxylating properties able to convert, in the presence of an alkyl halide, amines into the corresponding carbamate esters. Moderate to good yields of carbamates were obtained according to the nature of the amine and the alkylating agent.

Graphical abstract: BMIm HCO3: an ionic liquid with carboxylating properties. Synthesis of carbamate esters from amines

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Publication details

The article was received on 29 Aug 2016, accepted on 11 Oct 2016 and first published on 12 Oct 2016


Article type: Letter
DOI: 10.1039/C6NJ02705A
Citation: New J. Chem., 2016,40, 9895-9898
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    BMIm HCO3: an ionic liquid with carboxylating properties. Synthesis of carbamate esters from amines

    A. Di Nicola, A. Arcadi and L. Rossi, New J. Chem., 2016, 40, 9895
    DOI: 10.1039/C6NJ02705A

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