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Issue 12, 2016
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Effects of the incorporation of bithiophene instead of thiophene between the pyrrolo[3,4-c]pyrrole-1,3-dione units of a bis(pyrrolo[3,4-c]pyrrole-1,3-dione)-based polymer for polymer solar cells

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Abstract

A new wide band gap polymer, P(BDTT–BTBDPPD), consisting of electron rich 4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b:4,5-b′]dithiophene (BDTT) and electron deficient bithiophene-incorporated bis(pyrrolo[3,4-c]pyrrole-1,3(2H,5H)-dione) (BTBDPPD) derivative was prepared to improve the photovoltaic performances of a reported polymer, P(BDTT–TBDPPD), containing BDTT and thiophene-incorporated bis(pyrrolo[3,4-c]pyrrole-1,3(2H,5H)-dione) (TBDPPD) derivative. Polymer P(BDTT–BTBDPPD) exhibited maximum absorption at 478 nm and the calculated optical band gap was 2.10 eV. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of P(BDTT–BTBDPPD) were estimated to be −5.44 eV and −3.34 eV. The hole mobility of P(BDTT–BTBDPPD) was 3.22 × 10−4 cm2 V−1 s−1. The polymer solar cells (PSCs) prepared using P(BDTT–BTBDPPD) : PC70BM (1 : 2 wt%) + 3 vol% DIO blend offered a maximum power conversion efficiency (PCE) of 4.62% with an open-circuit voltage (Voc) of 0.90 V, a short-circuit current (Jsc) of 7.99 mA cm−2, and a fill factor (FF) of 64%. This study suggests that the replacement of the thiophene spacer unit located between the pyrrolo[3,4-c]pyrrole-1,3(2H,5H)-dione units of bis(pyrrolo[3,4-c]pyrrole-1,3(2H,5H)-dione) derivative with a bithiophene unit did not considerably alter the energy levels and charge transport properties of the resulting polymer. However, the overall photovoltaic performance was improved due mainly to the enhanced morphology of the photoactive layer.

Graphical abstract: Effects of the incorporation of bithiophene instead of thiophene between the pyrrolo[3,4-c]pyrrole-1,3-dione units of a bis(pyrrolo[3,4-c]pyrrole-1,3-dione)-based polymer for polymer solar cells

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Publication details

The article was received on 09 Aug 2016, accepted on 17 Oct 2016 and first published on 18 Oct 2016


Article type: Paper
DOI: 10.1039/C6NJ02478E
Citation: New J. Chem., 2016,40, 10153-10160
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    Effects of the incorporation of bithiophene instead of thiophene between the pyrrolo[3,4-c]pyrrole-1,3-dione units of a bis(pyrrolo[3,4-c]pyrrole-1,3-dione)-based polymer for polymer solar cells

    V. Tamilavan, S. Kim, J. Y. Sung, D. Y. Lee, S. Cho, Y. Jin, J. Jeong, S. H. Park and M. H. Hyun, New J. Chem., 2016, 40, 10153
    DOI: 10.1039/C6NJ02478E

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