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Issue 12, 2016
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Chiral 1,2-dithiine as a sulfur rich electron acceptor

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Abstract

The selective synthesis of both enantiomers of a sulfur rich electron acceptor containing two 1-phenylethyl groups of the same chirality and a chiral axis is described. Cyclisation into enantiopure dithiine has been induced by the presence of a chiral substituent on the nitrogen atom of a thiazoline-2-thione dithiolate precursor.

Graphical abstract: Chiral 1,2-dithiine as a sulfur rich electron acceptor

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Publication details

The article was received on 22 Jul 2016, accepted on 03 Oct 2016 and first published on 04 Oct 2016


Article type: Paper
DOI: 10.1039/C6NJ02292H
Citation: New J. Chem., 2016,40, 9930-9935
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    Chiral 1,2-dithiine as a sulfur rich electron acceptor

    Y. Le Gal, D. Ameline, A. Vacher, T. Roisnel, V. Dorcet and D. Lorcy, New J. Chem., 2016, 40, 9930
    DOI: 10.1039/C6NJ02292H

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