Jump to main content
Jump to site search

Issue 12, 2016
Previous Article Next Article

Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels

Author affiliations

Abstract

The application of a positive electric field on a Pd(0)–carbon aerogel nanocomposite enhances the reaction rate of the Mizoroki–Heck reaction. By contrast, when a negative potential is employed the reaction is inhibited. On the other hand, chronoamperometry measurements have revealed the polarizing current intensity as an indirect measure of the reaction evolution. The cationic nature of the reaction intermediates was unambiguously confirmed and a polar mechanism has been finally proposed.

Graphical abstract: Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels

Back to tab navigation

Supplementary files

Publication details

The article was received on 21 Jul 2016, accepted on 14 Oct 2016 and first published on 17 Oct 2016


Article type: Paper
DOI: 10.1039/C6NJ02279K
Citation: New J. Chem., 2016,40, 10208-10212
  • Open access: Creative Commons BY-NC license
  •   Request permissions

    Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels

    L. Martín, E. Molins and A. Vallribera, New J. Chem., 2016, 40, 10208
    DOI: 10.1039/C6NJ02279K

    This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements