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Issue 11, 2016
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Supramolecular homochiral helicity and zigzag hydrogen bonded chains in 1,2,4-triazole derived aminoester and aminoacid

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Abstract

Two precursors for coordination polymer design, namely ethyl-4H-1,2,4-triazol-4-yl-acetate (1) and 4-(4H-1,2,4-triazol-4-yl)L-propionic acid (2), were prepared via a transamination reaction followed by crystallization from MeOH. Single crystal X-ray data analysis revealed that 1 and 2 exhibit homochiral helical and 2D hydrogen bonded networks, respectively.

Graphical abstract: Supramolecular homochiral helicity and zigzag hydrogen bonded chains in 1,2,4-triazole derived aminoester and aminoacid

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Publication details

The article was received on 29 May 2016, accepted on 12 Sep 2016 and first published on 30 Sep 2016


Article type: Letter
DOI: 10.1039/C6NJ01687A
Citation: New J. Chem., 2016,40, 9025-9029
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    Supramolecular homochiral helicity and zigzag hydrogen bonded chains in 1,2,4-triazole derived aminoester and aminoacid

    M. M. Dîrtu, N. N. Adarsh, A. D. Naik, K. Robeyns and Y. Garcia, New J. Chem., 2016, 40, 9025
    DOI: 10.1039/C6NJ01687A

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