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Issue 11, 2016
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High temperature spin crossover in [Fe(pyrazine){Ag(CN)2}2] and its solvate

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Abstract

A high temperature spin crossover (Tup = 367 K) was detected in a metal–organic framework [Fe(pz){Ag(CN)2}2]·MeCN (pz = pyrazine). Upon heating, this solvate released acetonitrile guest molecules, which slightly shifted the transition temperature of the complex (Tup = 370 K and Tdown = 356 K).

Graphical abstract: High temperature spin crossover in [Fe(pyrazine){Ag(CN)2}2] and its solvate

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Publication details

The article was received on 10 May 2016, accepted on 12 Sep 2016 and first published on 13 Sep 2016


Article type: Letter
DOI: 10.1039/C6NJ01472K
Citation: New J. Chem., 2016,40, 9012-9016
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    High temperature spin crossover in [Fe(pyrazine){Ag(CN)2}2] and its solvate

    I. A. Gural'skiy, S. I. Shylin, B. O. Golub, V. Ksenofontov, I. O. Fritsky and W. Tremel, New J. Chem., 2016, 40, 9012
    DOI: 10.1039/C6NJ01472K

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