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Issue 7, 2016
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C–N bond hydrogenolysis of aniline and cyclohexylamine over TaOx–Al2O3

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Abstract

TaOx grafted onto Al2O3 is investigated for C–N bond cleavage of amines under H2 pressure. Heteroaromatics such as aniline are stoichiometrically denitrogenated at high temperature, while cyclohexylamine is catalytically denitrogenated. UV-visible and X-ray photoelectron spectroscopy indicate the formation of a stable Ta–N species in the former case.

Graphical abstract: C–N bond hydrogenolysis of aniline and cyclohexylamine over TaOx–Al2O3

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Publication details

The article was received on 07 Apr 2016, accepted on 23 May 2016 and first published on 24 May 2016


Article type: Letter
DOI: 10.1039/C6NJ01076H
Citation: New J. Chem., 2016,40, 6001-6004
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    C–N bond hydrogenolysis of aniline and cyclohexylamine over TaOx–Al2O3

    M. Bachrach, T. J. Marks and J. M. Notestein, New J. Chem., 2016, 40, 6001
    DOI: 10.1039/C6NJ01076H

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