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Issue 2, 2016
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Characterization of PtIV-containing polyoxometalates by high-resolution solid-state 195Pt and 51V NMR spectroscopy

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Abstract

We report on the feasibility of applying high-resolution solid-state 195Pt MAS NMR spectroscopy for several PtIV-containing polyoxotungstates, and of 195Pt as well as 51V for a PtIV-containing polyoxovanadate. This method is particularly useful for polyanions which are unstable in solution and/or poorly soluble, as well as for systems exhibiting crystallographic disorder of Pt and W sites. We also report solution 195Pt and 183W NMR spectra of hexatungstoplatinate(IV) [H3PtW6O24]5− for the first time.

Graphical abstract: Characterization of PtIV-containing polyoxometalates by high-resolution solid-state 195Pt and 51V NMR spectroscopy

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Publication details

The article was received on 20 May 2015, accepted on 09 Jul 2015 and first published on 29 Jul 2015


Article type: Paper
DOI: 10.1039/C5NJ01242B
Citation: New J. Chem., 2016,40, 923-927
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    Characterization of PtIV-containing polyoxometalates by high-resolution solid-state 195Pt and 51V NMR spectroscopy

    S. Dugar, N. V. Izarova, S. S. Mal, R. Fu, H. Joo, U. Lee, N. S. Dalal, M. T. Pope, G. B. Jameson and U. Kortz, New J. Chem., 2016, 40, 923
    DOI: 10.1039/C5NJ01242B

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