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Issue 19, 2016
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Visible-light induced oxidative Csp3–H activation of methyl aromatics to methyl esters

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Abstract

Direct functionalization of readily available hydrocarbons under mild conditions fulfills the requirements of green and sustainable chemistry. In this work, a mild and green catalytic oxidative Csp3–H activation of methyl aromatics using O2via photocatalysis has been achieved. A lot of methyl aromatics can be tolerated, providing a green route for aromatic methyl carboxylates. In addition, this protocol can be performed on a gram scale.

Graphical abstract: Visible-light induced oxidative Csp3–H activation of methyl aromatics to methyl esters

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Publication details

The article was received on 11 Jul 2016, accepted on 23 Aug 2016 and first published on 23 Aug 2016


Article type: Communication
DOI: 10.1039/C6GC01880G
Citation: Green Chem., 2016,18, 5122-5126
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    Visible-light induced oxidative Csp3–H activation of methyl aromatics to methyl esters

    L. Zhang, H. Yi, J. Wang and A. Lei, Green Chem., 2016, 18, 5122
    DOI: 10.1039/C6GC01880G

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