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Issue 21, 2016
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Supramolecular ensemble of PBI derivative and copper nanoparticles: a light harvesting antenna for photocatalytic C(sp2)–H functionalization

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Abstract

Supramolecular aggregates of triazole-appended perylene bisimide (PBI) derivative 3 served as reactors for the generation of copper nanoparticles (CuNPs). During the reduction process, these aggregates were oxidized to triazole N-oxide species 4. Interestingly, the in situ generated CuNPs, in combination with oxidized species 4 (supramolecular ensemble 4:CuNPs), exhibited excellent photocatalytic efficiency in C(sp2)–H alkynylation and amination reactions of arenes under mild and eco-friendly conditions (inexpensive catalyst, room temperature, mixed aqueous media, aerial conditions and visible light irradiation).

Graphical abstract: Supramolecular ensemble of PBI derivative and copper nanoparticles: a light harvesting antenna for photocatalytic C(sp2)–H functionalization

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Supplementary files

Publication details

The article was received on 24 Jun 2016, accepted on 09 Aug 2016 and first published on 09 Aug 2016


Article type: Paper
DOI: 10.1039/C6GC01728B
Citation: Green Chem., 2016,18, 5870-5883
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    Supramolecular ensemble of PBI derivative and copper nanoparticles: a light harvesting antenna for photocatalytic C(sp2)–H functionalization

    S. Kaur, M. Kumar and V. Bhalla, Green Chem., 2016, 18, 5870
    DOI: 10.1039/C6GC01728B

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